Beilstein J. Org. Chem.2015,11, 1017–1022, doi:10.3762/bjoc.11.114
: carbocationicrearrangement; cyclopentenones; furans; propargyl alcohols; Introduction
In the course of our medicinal program on a new class of anticancer agents [1][2][3], we developed a novel synthesis of cyclopentenones substituted by three different aryl groups (Scheme 1) [4]. This approach combines a
PDF
Graphical Abstract
Scheme 1:
Described synthesis of cyclopentenone 4 using a combination of Mo(VI) and Au(I)-catalyzed reactions...